but it will be good. White chocolate is the cocoa butter without the bitter dark chocolate liquor that gives chocolate its bite. The fat content is the same.
You might want to up the vanilla a tad just to make sure the cake tastes of something besides fat and sugar.
...dark chocolate is more alkaline than white chocolate. That can change the delicate balance of your leavening. That would have a big effect here in the high altitude but it might not be so critical at sea level.
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