http://www.nature.com/news/2008/081217/full/news.2008.1319.html Published online 17 December 2008 | Nature | doi:10.1038/news.2008.1319
News: Briefing
Sucking carbon out of the air
Are plans to take carbon dioxide out of the air just a pipe dream, or a cure for global warming?
Nicola Jones
…Are there any companies looking at this?
A few. Global Research Technologies, based in Tucson, Arizona, was founded in 2004 and is the biggest commercial name in the business. Graciela Chichilnisky and Peter Eisenberger of Columbia University also have a company, called Global Thermostat, founded in 2006. But many others are working in the field. David Keith of the University of Calgary in Canada is now raising funds and hopes to start a company called Carbon Engineering within a few months.How do their devices work?
There are various schemes. One main one first extracts CO2 from the air by dissolving it in sodium hydroxide (NaOH), giving a solution of sodium carbonate (Na2CO3). To get the carbon out of solution, a trick is borrowed from the pulp and paper industry: slaked lime (Ca(OH)2) or titanium dioxide (TiO2) is added to the mix. This creates particles — of limestone (CaCO3), if you're using lime — that settle out and can be collected. These particles are then thrown into a kiln and heated to release the CO2 and regenerate the material needed (slaked lime or titanium dioxide) to keep the system running. In effect, the entire system simply separates CO2 from air and concentrates it into a pure stream, so it's suitable for use or disposal.
This is the technique that Keith is pursuing, using a fine spray of liquid NaOH to suck up as much CO2 as possible. Keith calls it "Russian tractor" technology, because it is based on very conventional chemistry, scales up well and has a low technological risk. In the near term, says Keith, that makes it a solid bet.
Another idea is to use a solid ion-exchange resin, such as those found in the water-softening industry. This is the system being mainly pursued by Global Research Technologies. They have hit on a commercially sold resin that absorbs CO2 when dry, and releases it when exposed to humid air. This provides a very simple, low-energy way to mine CO2 from the air. But, Keith notes, if the resin proves vulnerable to contamination in scaled-up systems, that will be very hard to fix.
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