Moderators, please note, US Government sources. (Copyright concerns are nil.)
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Producing Rare Earth Oxides: No Small Task
A better appreciation of rare earth elements and the difficulty in acquiring them is attained by examining how they are processed. Dr. John Burba, Chief Technology Officer at Molycorp Minerals, the company that runs the only rare earth mining operation in the U.S., pointed out that, “a lot of people don’t quite understand why rare earth operations are different (from other mining operations).”
4 Mining gold, for example, is a much simpler procedure than mining rare earth elements. One method in processing gold ore, simply put, is to mix the ore with sodium cyanide. The gold is then leached right out.
Rare earth elements are far more complicated and costly to extract. (See Diagram 1 below) First, ore containing minerals (for this example, we will look at bastnaesite), is taken out of the ground using normal mining procedures. The bastnaesite must then be removed from the ore, which generally contains a number of other minerals of little value. The bastnaesite is removed by crushing the ore into gravel size, then placing the crushed ore into a grinding mill. Once the ore is ground down through a mill into a fine sand or silt the different mineral grains become separated from each other. The sand or silt is then further processed to separate the bastnaesite from the other nonessential minerals. This is accomplished by running the mixture through a floatation process. During the floatation process an agent is added and air bubbles come up through the bottom of the tank. Bastnaesite sticks to those bubbles and floats to the top of the tank as a froth, where it is then scraped off.
The bastnaesite contains the rare earth elements, which must be further separated into their respective pure forms in a separation plant, using acid and various solvent extraction separation steps. Each element has its own unique extraction steps and chemical processes and at times, these elements will require reprocessing to achieve the ideal purity. Once the elements are separated out, they are in the form of oxides, which can be dried, stored, and shipped for further processing into metals. The metals can be further processed into alloys and used for other applications such as the neodymium-iron-boron magnet. These alloys and magnets are then assembled into hundreds of high tech applications. In total, the process takes approximately 10 days from the point when the ore is taken out of the ground to the point at which the rare earth oxides are actually produced. The mining and processing of rare earth elements, if not carefully controlled, can create environmental hazards. This has happened in China.
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Severe environmental damage
A major concern surrounding China’s practice of mining rare earth elements is the negative impact it has to the environment due to lax mining practices. There are a number of potential environmental implications to mining rare earth elements if not done properly. Unfortunately, because of the revenue potential, many rare earth mines have been operating illegally, with no regulation, causing severe environmental hazards, which exacerbates the problem.
According to an article published by the Chinese Society of Rare Earths, “Every ton of rare earth produced, generates approximately 8.5 kilograms (18.7 lbs) of fluorine and 13 kilograms (28.7 lbs) of dust; and using concentrated sulfuric acid high temperature calcination techniques to produce approximately one ton of calcined rare earth ore generates 9,600 to 12,000 cubic meters (339,021 to 423,776 cubic feet) of waste gas containing dust concentrate, hydrofluoric acid, sulfur dioxide, and sulfuric acid, approximately 75 cubic meters (2,649 cubic feet) of acidic wastewater, and about one ton of radioactive waste residue (containing water).” Furthermore, according to statistics conducted within Baotou, where China’s primary rare earth production occurs, “all the rare earth enterprises in the Baotou region produce approximately ten million tons of all varieties of wastewater every year” and most of that waste water is “discharged without being effectively treated, which not only contaminates potable water for daily living, but also contaminates the surrounding water environment and irrigated farmlands.”
The disposal of tailings also contributes to the problem. Tailings are the ground up materials left behind once the rare earth has been extracted. Often, these tailings contain thorium, which is radioactive. Generally, tailings are placed into a large land impoundment and stored. In the U.S. strict controls are put into place and permits are required to store tailings. According to Wang Caifeng, China’s Deputy Director-General of the Materials Department of the Ministry of Industry and Information Technology, producing one ton of rare earth elements creates 2,000 tons of mine tailings. Wang said that China has sacrificed greatly in its extraction of rare earths.
34 While taking steps to solve the problem, China still has a long way to go before it achieves any semblance of control over the environmental damage that occurs from its mining and processing of rare earth elements. According to a representative of one Chinese factory in Baotou, Inner Mongolia, while companies will put some money toward more environmentally friendly mining processes, others opt to keep those expenses at a minimum to maintain their competitive edge in the market. The costs associated with environmental improvements are absorbed by the customers. Another factor within China’s industry is that the land belongs to the government and not to the factories. Therefore, if a rare earth producer pays a large sum of money for machinery or processes which are more environmentally friendly that investment could be suddenly lost because the government can choose to take back the land for any number of reasons such as building a new road through the property. This reduces the incentive to meet any type of environmental standards. Furthermore, the Chinese government does not provide any financial support to help companies meet environmental standards. The ore mined in Bayan Obo is transported to Baotou via open railway carts, where it is then processed. Unfortunately, with old, outdated technology, equipment, and little oversight, the waste finds its way into the Yellow River, which passes by the south side of Baotou and travels about another 1,300 miles, through mountainous terrain as well as through heavily populated areas before finally dumping into the Yellow Sea.
In 2005, Xu Guangxian wrote that thorium was a source of radioactive contamination in the Baotou area and the Yellow River.
35 According to a local source, who asked not to be identified, “In the Yellow River, in Baotou, the fish all died. They dump the waste – the chemicals into the river. You cannot eat the fish because they are polluted.” Some 150 million people depend on the river as their primary source of water.
36Under traditional technology means, refining rare earth elements requires such chemicals as ammonium bicarbonate and oxalic acid. The potential health hazards of ammonium bicarbonate include: Irritation to the respiratory tract if inhaled, irritation to the gastrointestinal tract if ingested, redness and pain if it comes in contact with the eyes, and redness, itching, and pain if it comes in contact with the skin.
37 Oxalic acid is poisonous and potentially fatal if swallowed. It is also corrosive and causes severe irritation and burns to the skin, eyes, and respiratory tract, is harmful if inhaled or absorbed through the skin, and can cause kidney damage.
38 These and other chemicals often find their way into the Yellow River.
Safety standards in China are lax. “People in their 30s have died of cancer working around the mines, possibly from radioactive materials,” said one local source. “I visited a factory many times. When I visit a factory or workshop, I tell the director of the workshop, ‘would you tell the laborers to put their mask on when they are doing their job?’ He said, ‘Oh yeah. We do every time, but it’s too hot. They don’t want to keep their mask on.’ You can see that the air is dirty and they are breathing it all in.” The most common disease in Baotou is pneumoconiosis, better known as black lung. There are 5,387 residents in Baotou who suffer from black lung, which makes up more than 50 percent of the cases in the autonomous region.
39While China might have general pollution control standards, the country has never actually worked out pollutant discharge standards for the rare earth industry. As the rare earth industry in China has rapidly grown, there has been no effective way to control the usual pollutants such as ammonia, nitrogen, and thorium dust, which are emitted during the production phase. Furthermore, general health and safety regulations are often ignored for a number of reasons, including:
- The industry is large and challenging to monitor.
- People and companies are not being held accountable. For example, in Western society, if an employee dies or becomes ill, repercussions could include a lawsuit or life-long pension which the company is obligated to fulfill. This is not the case in China.
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